103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^* Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45