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23April2017

Prof. Qi-Lin Zhou's Research Group

周其林教授课题组主页

 

 Shou-Fei Zhu(朱守非)

 Professor

中文简历

 PERSONAL
 Date of birth & place  Nov. 27, 1977, Anhui province,China
 Work Address  Institute of Elemento-Organic Chemistry
 Nankai University
 94 Wenjin Road, Tianjin 300071
 Telephone  +86-(0)22-2350-4087
 Fax  +86-(0)22-2350-4087
 E-mail:   This email address is being protected from spambots. You need JavaScript enabled to view it.

Educational Background

1996.09-2000.06  B.Sc., Nankai University (Advisor: Prof. Shou-He Xiang)
2000.09-2005.06  Ph.D., Nankai University (Advisor: Prof. Qi-Lin Zhou)
2012.03-2013.03 Postdoctoral Fellow, the University of Tokyo (Advisor: Prof. Eiichi Nakamura)


Professional Career

2005.07-2008.12 Lecture, Nankai University
2008.12-2013.12 Associate Professor, Nankai University
2013.12-present, Professor, Nankai University


Research Interests

SFZ's research interests focus on catalytic organic synthesis, particularly those involving hydrogen transfer as key steps. He developed novel “chiral proton shuttle” catalysts for metal-catalyzed reactions, which can realize efficient chiral control of proton transfer of active intermediates and have been recognized as “an area poised for further development”. He developed a catalytic insertion reaction of carbene into B‒H bond, which contains a critical hydrogen atom transfer process and provide “an attractive approach to chiral organoborons”. Moreover, he also developed various efficient transition-metal catalysts for the hydrogenation and hydrosilylation, which contain metal-hydride transfers as key steps and have been used for preparing bioactive compounds.


Honors and Awards

2016 National Outstanding Young Investigator (National Natural Science Foundation of China)

2016 Chang Jiang Scholars Program for Young Scholars

2016 Tianjin Youth Wu-Si Medal

2015 Youth Science and Technology Innovation Leader (Ministry of Science and Technology of China) 

2015 Tianjin Youth Science and Technology Innovation Leader

2015 Tianjin 131 Creative Talents Cultivation Project (First Class)

2015 Asian Core Program Lectureship Awards (from Hong Kong and Korea)

2015 Nankai-Jebsen Scholarships for Teachers

2014 Tianjin 131 Creative Talents Cultivation Project (Second Class)

2013  National Program for Support of Top-notch Young Professionals

2013  The 12th Tianjin Youth Award for Science and Technology

2013  Tianjin Natural Science Award (the First-Rank)

2013  The 100 Young-Academic-Leader Project of Nankai University

2012  The Science Funds for Excellent Youth (The National Natural Science Foundation of China)

2012  Young Chemist Award of Chinese Chemical Society

2010  the Program for New Century Excellent Talents in University (The Ministry of Education of China)

2007  Tianjin Natural Science Award (the First-Rank)

2004  Hong Kong Qiu-Shi Award for Graduate Students


Research Papers

1. Shou-Fei Zhu*, Qi-Lin Zhou*, Iridium-catalyzed asymmetric hydrogenation of unsaturated carboxylic acids, Acc. Chem. Res. 2017, DOI: 10.1021/acs.accounts.7b00007.

2. Ji-Min Yang, Zi-Qi Li, Mao-Lin Li, Qiao He, Shou-Fei Zhu*, Qi-Lin Zhou*, Catalytic B–H bond insertion reactions using alkynes as carbene precursors, J. Am. Chem. Soc. 2017, 139, 3784‒3789.

3. Mao-Lin Li, Shuang Yang, Xun-Cheng Su, Hui-Ling Wu, Liang-Liang Yang, Shou-Fei Zhu*, Qi-Lin Zhou*, Mechanism studies of Ir-catalyzed asymmetric hydrogenation of unsaturated carboxylic acids, J. Am. Chem. Soc. 2017, 139, 541‒547.

4. Shuang Yang, Wen Che, Hui-Ling Wu, Shou-Fei Zhu*, Qi-Lin Zhou*, Neutral iridium catalysts with chiral phosphine-carboxy ligands for asymmetric hydrogenation of unsaturated carboxylic acids, Chem. Sci. 2017, 8, 1977‒1980.

5. Qing-Qing Cheng, Ji-Min Yang, Huan Xu, Shou-Fei Zhu*, Iron-catalyzed carbenoid insertion into C(sp3)‒H bonds, Synlett 2017, DOI: 10.1055/s-0036-1588743.

6. Jun-Xia Guo, Ting Zhou, Bin Xu, Shou-Fei Zhu*, Qi-Lin Zhou, Enantioselective synthesis of α-alkenyl α-amino acids via N–H insertion reactions, Chem. Sci. 2016, 7, 1104‒1108. (Highlighted by Synfacts 2016, 12, 160; Org. Chem. Portal 2017/02/13)

7. Ming-Lei Yuan, Jian-Hua Xie, Shou-Fei Zhu, Qi-Lin Zhou*, Deoxygenative hydrogenation of amides catalyzed by a well-defined iridium pincer complex. ACS. Catal. 2016, 6, 3665‒3669.

8. Yan-Bo Yu, Lei Cheng, Yi-Pan Li, Yue Fu, Shou-Fei Zhu*, Qi-Lin Zhou*, Enantioselective iridium-catalyzed hydrogenation of β,β-disubstituted nitroalkenes, Chem. Commun. 2016, 52, 4812‒4815. (Highlighted by Synfacts 2016, 12, 712)

9. Xiao-Guang Song, Yuan-Yuan Ren, Shou-Fei Zhu*, Qi-Lin Zhou*, Enantioselective copper-catalyzed intramolecular N–H bond insertion: synthesis of chiral 2-carboxytetrahydroquinolines, Adv. Synth. Catal. 2016, 358, 2366‒2370. (Highlighted by Synfacts 2016, 12, 1158)

10. Honglei Liu, Yang Liu, Chunhao Yuan, Guo-Peng Wang, Shou-Fei Zhu, Yang Wu, Bo Wang, Zhanhu Sun, Yumei Xiao, Qi-Lin Zhou*, Hongchao Guo*, Enantioselective synthesis of spirobarbiturate-cyclohexenes through phosphine-catalyzed asymmetric [4 + 2] annulation of barbiturate-derived alkenes with allenoates, Org. Lett. 2016, 18, 1302‒1305.

11. Ji-Min Yang, Yan Cai, Shou-Fei Zhu*, Qi-Lin Zhou, Iron-catalyzed arylation of α-aryl-α-diazoesters. Org. Biomol. Chem. 2016, 14, 5516‒5519. (Invited for special issue of “New Talents”)

12. Bin Xu, Mao-Lin Li, Xiao-Dong Zuo, Shou-Fei Zhu*, Qi-Lin Zhou, Catalytic asymmetric arylation of α-aryl-α-diazoacetates with aniline derivatives, J. Am. Chem. Soc. 2015, 137, 8700‒8703. (Highlight by Synfacts 2015, 11, 1061; X-Mol 2015/10/10).

13. Cui Guo, Dong-Wei Sun, Shuang Yang, Shen-Jie Mao, Xiao-Hua Xu*, Shou-Fei Zhu*, Qi-Lin Zhou*, Iridium-catalyzed asymmetric hydrogenation of 2-pyridyl cyclic imines: a highly enantioselective approach to nicotine derivatives, J. Am. Chem. Soc. 2015, 137, 90‒93. (Highlighted by Synfacts 2015, 11, 296)

14. Paula Mayorga Burrezo, Xiaozhang Zhu, Shou-Fei Zhu, Qifan Yan, Juan T. López Navarrete*, Hayato Tsuji*, Eiichi Nakamura*, and Juan Casado*, Planarization, fusion, and strain of carbon-bridged phenylenevinylene oligomers enhance π-electron and charge conjugation: a dissectional vibrational raman study, J. Am. Chem. Soc. 2015, 137, 3834‒3843.

15. De Wang, Guo-Peng Wang, Yao-Liang Sun, Shou-Fei Zhu, Yin Wei, Qi-Lin Zhou*, Min Shi*, Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones, Chem. Sci. 2015, 6, 7319‒7325.

16. Na Guo, Meng-Yang Hu, Ye Feng, Shou-Fei Zhu*, Highly efficient and practical hydrogenation of olefins catalyzed by in situ generated iron complex catalysts, Org. Chem. Front. 2015, 2, 692‒696.

17. Qing-Qing Cheng, Huan Xu, Shou-Fei Zhu*, Qi-Lin Zhou, Enantioselective copper-catalyzed B‒H bond insertion reaction of α-diazoketones, Acta Chim. Sinica 2015, 73, 326‒329. (Cover story).

18. Na Guo, Shou-Fei Zhu*, Iron-catalyzed hydrogenation reactions, Chin. J. Org. Chem. 2015, 35, 1383‒1398. (Cover story).

19. Jun-Jie Shen, Shou-Fei Zhu*, Yan Cai, Huan Xu, Xiu-Lan Xie, Qi-Lin Zhou, Enantioselective iron-catalyzed intramolecular cyclopropanation reactions, Angew. Chem. Int. Ed. 2014, 53, 13188‒13191. (Highlighted by Synfacts 2014, 10, 1284; Org. Chem. Portal 2015/08/10).

20. Bin Xu, Shou-Fei Zhu*, Xiao-Dong Zuo, Zhi-Chao Zhang, Qi-Lin Zhou*, Enantioselective N‒H insertion reaction of α-aryl α-diazoketones: an efficient access to chiral α-aminoketones, Angew. Chem. Int. Ed. 2014, 53, 3913‒3916. (Selected as a VIP paper; Highlighted by Synfacts 2014, 10, 0534).

21. Xiu-Lan Xie, Shou-Fei Zhu*, Jun-Xia Guo, Yan Cai, Qi-Lin Zhou*, Enantioselective palladium-catalyzed insertion of α-aryl-α-dizaoesters into the O‒H bonds of phenols, Angew. Chem. Int. Ed. 2014, 53, 2978‒2981. (Selected as a Hot Paper; Highlighted by ACS Noteworthy Chemistry, 2014, April 21; Synfacts 2014, 10, 0611; Chin. J. Org. Chem. 2014, 34, 1034; Org. Chem. Portal 2015/02/09).

22. Bin Xu, Shou-Fei Zhu*, Zhi-Chao Zhang, Zhi-Xiang Yu*, Yi Ma, Qi-Lin Zhou*, Highly enantioselective S-H insertion reaction cooperatively catalyzed by dirhodium complexes and chiral spiro posphonic acids, Chem. Sci. 2014, 5, 1442‒1448. (Highlighted by Synfacts 2014, 10, 0432).

23. Shuang Yang, Shou-Fei Zhu, Na Guo, Song Song, Qi-Lin Zhou*, Carboxy-directed asymmetric hydrogenation of α-alkyl-α-aryl terminal olefins: highly enantioselective and chemoselective access to a chiral benzylmethyl center, Org. Biomol. Chem. 2014, 12, 2049–2052. (Selected as a Hot Paper).

24. Ze-Yu Li, Song Song, Shou-Fei Zhu*, Na Guo, Li-Xin Wang, Qi-Lin Zhou*, Synthesis of chiral α-benzyl-β2-hydroxy carboxylic acids through iridium-catalyzed asymmetric hydrogenation of α-oxymethylcinnamic acids, Chin. J. Chem. 2014, 32, 783‒787.

25. Shou-Fei Zhu*, Qi-Lin Zhou*, Iron-catalyzed transformations of dizao compounds, National Science Review 2014, 1, 580–603. 

26. Qing-Qing Cheng, Shou-Fei Zhu*, Yong-Zhen Zhang, Xiu-Lan Xie, Qi-Lin Zhou*, Copper-catalyzed B–H bond insertion reaction: a highly efficient and enantioselective C–B bond-forming reaction with amine- and phosphine-borane adducts, J. Am. Chem. Soc. 2013, 135, 14094–14097. (Highlighted by Synfacts 2013, 9, 1323).

27. Song Song, Shou-Fei Zhu, Liu-Yang Pu, Qi-Lin Zhou*, Iridium-catalyzed enantioselective hydrogenation of unsaturated heterocyclic acids, Angew. Chem. Int. Ed. 2013, 52, 6072–6075. (Highlighted by Org. Chem. Portal 2013/11/18).

28. Xiao-Guang Song, Shou-Fei Zhu, Xiu-Lan Xie, Qi-Lin Zhou*, Enantioselective copper-catalyzed intramolecular phenolic O‒H bond insertion: synthesis of chiral 2-carboxy dihydrobenzofurans, dihydrobenzopyrans, and tetrahydrobenzooxepines, Angew. Chem. Int. Ed. 2013, 52, 2555–2558.

29. Song Song, Shou-Fei Zhu, Yan-Bo Yu, Qi-Lin Zhou*, Carboxy-directed asymmetric hydrogenation of 1,1-diarylethenes and 1,1-dialkylethenes, Angew. Chem. Int. Ed. 2013, 52, 1556–1559. (Highlighted by T. Besset, R. Gramage-Doria, J. N. H. Reek, in Angew. Chem. Int. Ed. 2013, 52, 8795–8797).

30. Song Song, Shou-Fei Zhu, Yu Li, Qi-Lin Zhou*, Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids with tetrasubstituted olefins, Org. Lett. 2013, 15, 3722–3725.

31. Kang-Lun Huang, Cui Guo, Li-Jie Cheng, Long-Guan Xie, Qi-Lin Zhou, Xiao-Hua Xu*, Shou-Fei Zhu*, Enantioselective palladium-catalyzed ring-opening reaction of azabenzonorbornadienes with methyl 2-iodobenzoate: an efficient access to cis-dihydro benzo[c]phenanthridinones, Adv. Synth. Catal. 2013, 355, 2833–2838. (Highlighted by Synfacts 2014, 10, 0057).

32. Gang Li, Jian-Hua Xie*, Jing Hou, Shou-Fei Zhu, Qi-Lin Zhou*, Catalytic asymmetric hydrogenation of α-arylcyclohexanones and total synthesis of (−)-α-Lycorane, Adv. Synth. Catal. 2013, 355, 1597–1604.

33. Bo Zhang, Shou-Fei Zhu*, Qi-Lin Zhou*, Copper-catalyzed benzylic oxidation of C(sp3)-H bonds, Tetrahedron 2013, 69, 2033–2037.

34. Bo Zhang, Shou-Fei Zhu*, Qi-Lin Zhou*, Enantioselective copper-catalyzed allylic oxidation of acyclic olefins, Tetrahedron Lett. 2013, 54, 2665–2668.

35. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom-hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365–1377. 

36. Jian-Hua Xie,* Shou-Fei Zhu, Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev. 2012, 41, 4126–4139.

37. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, Qi-Lin Zhou*, Well-defined binuclear chiral spiro copper catalysts for enantioselective N–H insertion, J. Am. Chem. Soc. 2012, 134, 436–442.

38. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective hydrogenation of α-substituted acrylic acids catalyzed by iridium complexes with chiral spiro aminophosphine ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875.

39. Song Song, Shou-Fei Zhu, Shuang Yang, Shen Li, Qi-Lin Zhou*, Enantioselective iridium-catalyzed hydrogenation of β,γ-unsaturated carboxylic acids: an efficient approach to chiral 4-alkyl-4-aryl butanoic acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711.

40. Shou-Fei Zhu, Tao Liu, Shuang Yang, Song Song, Qi-Lin Zhou*,  Enantioselective hydrogenation of (Z)- and (E)-β-arylenamides catalyzed by rhodium complexes of monodentate chiral spiro phosphorous ligands: a new access to chiral β-arylisopropylamines, Tetrahedron 2012, 68, 7685–7690.

41. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*, Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172–5178.

42. Jian-Hua Xie, Shou-Fei Zhu, Qi-Lin Zhou*, Transition metal-catalyzed enantioselective hydrogenation of enamines and imines, Chem. Rev. 2011, 111, 1713‒1760.

43. Bin Xu, Shou-Fei Zhu*, Xiu-Lan Xie, Jun-Jie Shen, Qi-Lin Zhou*, Asymmetric N–H insertion reaction cooperatively catalyzed by rhodium and chiral spiro phosphoric acids, Angew. Chem. Int. Ed. 2011, 50, 11483‒11486.

44. Shou-Fei Zhu, Xiang-Chen Qiao, Yong-Zhen Zhang, Li-Xin Wang, Qi-Lin Zhou*, Highly enantioselective palladium-catalyzed umpolung allylation of aldehydes, Chem. Sci. 2011, 2, 1135‒1140.

45. Qiu-Shi Wang, Jian-Hua Xie, Wei Li, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Ruthenium-catalyzed hydrovinylation of N-acetylenamines leading to amines with a quaternary carbon center, Org. Lett. 2011, 13, 3388‒3391.

46. Yan Cai, Shou-Fei Zhu, Guo-Peng Wang, Qi-Lin Zhou*, Iron-catalyzed C-H fuctionalization of indoles, Adv. Synth. Catal. 2011, 353, 2939‒2944.

47. Shou-Fei Zhu, Wang-Qiao Chen, Qian-Qian Zhang, Hong-Xiang Mao, Qi-Lin Zhou*, Enantioselective copper-catalyzed O–H insertion of α-diazo phosphonates, Synlett 2011, 919‒922.

48. Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Jian-Hua Xie, Qi-Lin Zhou*, Enantioselective iron-catalysed O–H bond insertions, Nature Chemistry 2010, 2, 546–551. (Highlighted by Nature China with a title of Catalysis: The right metal for a sustainable future; Chemistry World with a title of Iron catalyst breaks the mould; Org. Chem. Portal 2011/7/11)

49. Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, Qi-Lin Zhou*, Enantioselective copper-catalyzed intramolecular O-H insertion: an efficient approach to chiral 2-carboxy cyclic ethers, J. Am. Chem. Soc. 2010, 132, 16374–16376.

50. Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective nickel-catalyzed reductive coupling of alkynes and imines, J. Am. Chem. Soc. 2010, 132, 10955–10957.

51. Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang, Qi-Lin Zhou*, Enantioselective hydrogenation of α-aryloxy and α-alkoxy α,β-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes, J. Am. Chem. Soc. 2010, 132, 1172–1179. (Highlighted by Org. Chem. Portal 2011/1/24)

52. Qing-Gang Wang, Shou-Fei Zhu, Long-Wu Ye, Chang-Yue Zhou, Xiu-Li Sun, Yong Tang*, Qi-Lin Zhou*, Catalytic asymmetric intramolecular cascade reaction for the construction of functionalized benzobicyclo[4.3.0] skeletons. Remote control of enantioselectivity, Adv. Synth. Catal. 2010, 352, 1914–1919.

53. Xiang-Chen Qiao, Shou-Fei Zhu, Wang-Qiao Chen, and Qi-Lin Zhou*, Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols, Tetrahedron: Asymmetry 2010, 21, 1216–1220.

54. Qi Zhang, Shou-Fei Zhu, Yan Cai, Li-Xin Wang, Qi-Lin Zhou*, Nickel-catalyzed enantioselective hydrovinylation of silyl-protected allylic alcohols: an efficient access to homoallylic alcohols with a chiral quaternary center, Sci. China Chem. 2010, 53, 1899–1906.

55. Yong-Zhen Zhang, Shou-Fei Zhu, Yan Cai, Hong-Xing Mao, Qi-Lin Zhou*, Copper-catalyzed enantioselective carbenoid insertion into S–H bonds, Chem. Commun. 2009, 5362–5364. (Highlighted by Synfacts 2009, 12, 1372) 

56. Xiang-Chen Qiao, Shou-Fei Zhu, Qi-Lin Zhou*, From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins, Tetrahedron: Asymmetry 2009, 20, 1254–1261.

57. Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou, Qi-Lin Zhou*, Nickel-catalyzed enantioselective alkylative coupling of alkynes and aldehydes: synthesis of chiral allylic alcohols with tetrasubstituted olefins, J. Am. Chem. Soc. 2008, 130, 14052–14053. (Highlighted by Synfacts 2009, 1, 58)

58. Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Qi-Lin Zhou*, Iridium-catalyzed enantioselective hydrogenation of a,b-unsaturated carboxylic acids, J. Am. Chem. Soc. 2008, 130, 8584–8585. (Highlighted by Synfacts 2008, 10, 1070)

59. Yong-Zhen Zhang, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Copper-catalyzed highly enantioselective carbeniod insertion into Si–H bond, Angew. Chem. Int. Ed. 2008, 47, 8496–8498. (Highlighted by Synfacts 2009, 1, 55)

60. Shou-Fei Zhu, Chao Chen, Yan Cai, Qi-Lin Zhou*, Catalytic asymmetric reaction with water: enantioselective synthesis of α-hydroxyesters by copper-carbenoid O–H insertion reaction, Angew. Chem. Int. Ed. 2008, 47, 932–934. (Highlighted by Synfacts 2008, 4, 392)

61. Feng Zhang, Yong Li, Zhi-Wei Li, Yan-Mei He, Shou-Fei Zhu, Qing-Hua Fan*, and Qi-Lin Zhou*, Modular chiral dendritic monodentate phosphoramidite ligands for Rh(II)-catalyzed asymmetric hydrogenation: unprecedented enhancement of enantioselectivity, Chem. Commun. 2008, 6048–6050.

62. Qi Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*, Nickel-catalyzed highly selective hydrovinylation of α-ketals of vinylarenes, Adv. Synth. Catal. 2008, 350, 1507–1510.

63. Wei Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Qi-Lin Zhou*, Highly enantioselective copper-catalyzed ring opening of oxabicyclic alkenes with Grignard reagents, Chem. Asian J. 2008, 3, 2105–2111.

64. Chao Chen, Shou-Fei Zhu, Bin Liu, Li-Xin Wang, Qi-Lin Zhou*, Highly enantioselective insertion of carbenoids into O–H bonds of phenols: an efficient approach to chiral α-aryloxycarboxylic esters, J. Am. Chem. Soc. 2007, 129, 12616–12617. (Highlighted by Synfacts 2008, 1, 47)

65. Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, Qi-Lin Zhou*, Highly enantioselective insertion of carbenoids into N–H bonds catalyzed by copper complexes of chiral spiro bisoxazolines, J. Am. Chem. Soc. 2007, 129, 5834–5835. (Highlighted by C. J. Moody, Angew. Chem. Int. Ed. 2007, 46, 9148–9150; Synfacts 2007, 7, 713)

67. Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, Qi-Lin Zhou*, Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: highly enantioselective synthesis of chiral bishomoallylic alcohols, J. Am. Chem. Soc. 2007, 129, 2248–2249. (Highlighted by Synfacts 2007, 5, 517)

68. Yi-Xia Jia, Jun Zhong, Shou-Fei Zhu, Can-Ming Zhang, Qi-Lin Zhou*, Chiral Brønsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and α-aryl enamides: construction of chiral quaternary carbon atoms, Angew. Chem. Int. Ed. 2007, 46, 5565–5567. (Highlighted by Synfacts 2007, 9, 992) 

69. Wei-Jun Tang, Shou-Fei Zhu, Li-Jin Xu*, Qi-Lin Zhou, Qing-Hua Fan*, Hai-Feng Zhou, Kimhung Lam, Albert S. C. Chan*, Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio, Chem. Commun. 2007, 613–615.

70. Shou-Fei Zhu, Jian-Bo Xie, Yong-Zhen Zhang, Shen Li, Qi-Lin Zhou*, Well-defined chiral spiro iridium/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure, J. Am. Chem. Soc. 2006, 128, 12886–12891.

71. Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, Qi-Lin Zhou*, Highly enantioselective hydrovinylation of α-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters, J. Am. Chem. Soc.2006, 128, 2780–2781. (Highlighted by Synfacts2006, 7, 707; Org. Chem. Portal 2007/2/19)

72. Yi-Xia Jia, Shuo-Fei Zhu, Yun Yang, Qi-Lin Zhou*, Asymmetric Friedel-Crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes, J. Org. Chem. 2006, 71, 75–80.

73. Xu Cheng, Shou-Fei Zhu, Xiang-Chen Qiao, Pu-Cha Yan, Qi-Lin Zhou*, A general synthetic route to chiral dihydroxy-9,9’-spirobifluorenes, Tetrahedron 2006, 62, 8077–8082.

74. Chao Chen, Shou-Fei Zhu, Xin-Yan Wu*, Qi-Lin Zhou*, Preparation and application of chiral spiro nitrogen-containing ligands for cobalt-catalyzed asymmetric Michael addition, Tetrahedron: Asymmetry 2006, 17, 2761–2767.

75. Bin Liu, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Preparation and application of bisoxazoline ligands with a chiral spirobiindane skeleton for asymmetric cyclopropanation and allylic oxidation, Tetrahedron: Asymmetry 2006, 17, 634–641.

76. Man Jiang, Shou-Fei Zhu, Yun Yang, Liu-Zhu Gong, Xiang-Ge Zhou*, Qi-Lin Zhou*, Asymmetric aldol reactions catalyzed by new spiro diamine derivatives, Tetrahedron: Asymmetry 2006, 17, 384–387.

77. Shou-Fei Zhu, Yun Yang, Li-Xin Wang, Bin Liu, Qi-Lin Zhou*, Synthesis and application of chiral spiro phospholane ligand in Pd-catalyzed asymmetric allylation of aldehydes with allylic alcohols, Org. Lett. 2005, 7, 2333–2335. (Highlighted by Synfacts 2005, 1, 0145)

78. Jian-Hua Xie, Shou-Fei Zhu, Yu Fu, Ai-Guo Hu, Qi-Lin Zhou*, New chiral phosphorus ligands with spirobiindane backbone for the asymmetric hydrogenations, Pure Appl. Chem. 2005, 77, 2121–2132. (An account paper) 

79. Yu Fu, Xun-Xiang Guo, Shou-Fei Zhu, Ai-Guo Hu, Jian-Hua Xie, Qi-Lin Zhou*, Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands, J. Org. Chem. 2004, 69, 4648–4655.

80. Jian-Hua Xie, Li-Xin Wang, Yu Fu, Shuo-Fei Zhu, Bao-Min Fan, Hai-Feng Duan, Qi-Lin Zhou*, Synthesis of spiro diphosphine ligands and their application in asymmetric hydrogenation of ketones, J. Am. Chem. Soc. 2003, 125, 4404–4405.

81. Shou-Fei Zhu, Yu Fu, Jian-Hua Xie, Bin Liu, Liang Xing, Qi-Lin Zhou*, Synthesis of chiral 4,4’-disubstituted-1,1’-spirodiindane-7,7′-diols and related phosphoramidites: the substituent effected of SIPHOS ligands in Rh-catalyzed asymmetric hydrogenation, Tetrahedron: Asymmetry 2003, 14, 3219–3224.

82. Wen-Jian Shi, Li-Xin Wang, Yu Fu, Shou-Fei Zhu, Qi-Lin Zhou*, Highly regioselective asymmetric copper-catalyzed allylic alkylation with dialkylzincs using monodentate chiral spiro phosphoramidite and phosphite ligands, Tetrahedron: Asymmetry 2003, 14, 3867–3872.

83. Ju-Hua Zhang, Jian Liao, Xin Cui, Kai-Bei Yu, Jin Zhu, Jin-Gen Deng*, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Lung Wa Chung, Tao Ye*, Highly efficient and practical resolution of 1,1’-spirobiindane-7,7’-diol by inclusion crystallization with N-benzylcinchonidinium chloride, Tetrahedron: Asymmetry 2002, 13, 1363–1366.


Book Chapters

1. Shou-Fei Zhu and Qi-Lin Zhou, Spiro Ligands for Asymmetric Catalysis, in Ligand Design in Metal Chemistry, by Mark Stradiotto and Rylan Lundgren (Editors), Wiley-VCH, 2016.

2. Shou-Fei Zhu and Qi-Lin Zhou, Chiral Spiro Ligands, as Chapter 4 of Privileged Chiral Ligands and Catalysts, by Qi-Lin Zhou (Editor), Wiley-VCH, 2011.


Patents

1. 周其林,朱守非,杨爽,车稳,王立新,一种新型螺环膦-羧酸的铱络合物及其制备方法和应用,申请号:201610922754.1申请日期:20161028日。

2. 朱守非,胡梦阳,贺荞,王立新,2,9 -二芳基取代邻菲啰啉与其铁络合物和制备方法及其应用,申请号:201610546418.1,申请日期:2016713日。

3. Qi-Lin Zhou, Shou-Fei Zhu, Yan-Bo Yu, Shen Li, and Li-Xin Wang, Preparation of spiro benzylic amino-phosphine ligands and their applications thereof, PCT Int. Appl. 2011, PCT/CN2012/079257, WO 2013029446. Also published as CN 102391306.【周其林,朱守非,余艳波,李珅,王立新,螺环苄胺-膦和制备方法及其应用,公开号:CN 102391306,专利号:ZL201110252000.7,授权日期:201493日。】

4. Qi-Lin Zhou, Shou-Fei Zhu, Shen Li, Li-Xin Wang, and Song Song, Preparation of spiro phosphine-oxazoline iridium(I) complexes as catalyst for asymmetric hydrogenation of unsaturated carboxylic acids, PCT Int. Appl. 2009, PCT/CN2009/070229, WO 2009129700. Also published as: CN 101565434. 【周其林,朱守非李珅,王立新,宋颂,螺环膦-噁唑啉和制备方法及其应用,公开号:CN 101565434,专利号:ZL200810052879.9,授权日期:2012530日。】

5. Qi-Lin Zhou, Shen Li, Shou-Fei Zhu, Can-Ming Zhang, and Li-Xin Wang, Application of the chiral spiro iridium phosphine-oxazoline cationic complexes in asymmetric catalytic hydrogenation of unsaturated carboxylic acid, PCT Int. Appl. 2009, PCT/CN2009/070231, WO 2009129701. Also published as: CN 101565366.【周其林,李珅,朱守非,张灿明,王立新,铱络合物在不饱和羧酸不对称催化氢化中的应用,公开号:CN 101565366,专利号:ZL200810052884.X,授权日期:2013417日。】

6. 周其林,朱守非,蔡艳,王立新,一种新型手性铁络合物及其制备方法和应用,公开号:CN 101412738,专利号:ZL200810203241.0,授权日期:2013424日。

7. 周其林,朱守非,王立新,螺环膦-噁唑啉配体及其在不对称催化氢化反应中的应用,公开号:CN 1884290,专利号:ZL200610014746.3,授权日期:20081112日。


Presentations at Scientific Meetings and Symposia 

1. 2017/01/13, Chinese University of Hong Kong, Lecture: Catalytic hydrogen transfer reactions. 

2. 2017/01/12, Hong Kong Baptist University, Lecture: Catalytic hydrogen transfer reactions.

3. 2017/01/11,New Frontiers in Homogeneous Catalysis, Hong Kong University of Science and Technology, Invited Lecture: Catalytic hydrogen transfer reactions.

4. 2016/11/04,湖南科技大学,报告题目:催化不对称氢转移反应。

5. 2016/10/06-08,2016年度京津有机化学沙龙(北京),专题报告:质子转移的手性控制策略。 

6. 2016/09/24-26,第18届中国科协年会(西安),邀请报告:手性质子梭催化剂。 

7. 2016/09/18-21,手性中国2016(北京),邀请报告:催化不对称氢转移反应。 

8. 2016/07/01-04,中国化学会第30届年会(大连),邀请报告:铁催化氢化和硅氢化反应研究。 

9. 2016/04/11-16, China-German Bilateral Symposium (Beijing), Invited Lecture: The development of chiral proton shuttle catalysts in transition-metal catalysis. 

10. 2016/03/29, The 1st Nankai-Hokkaido Bilateral Symposium, Invited Lecture: Chiral proton shuttles catalysts for asymmetric carbene insertion reactions. 

11. 2016/03/21-24, 2016 EMN Hawaii Meeting (Hawaii, USA), Invited Lecture: Chiral phosphoric acids: proton shuttle catalysts in transition-metal catalysis.

12. 2016/03/17, The University of Tokyo, Lecture: Transition-metal-catalyzed hydrogen transfer reactions.

13. 2015/12/15-20, Pacifichem 2015 (USA, Hawaii) (Co-organizer)

14. 2015/11/02-05, The 10th International Conference on Cutting-Edge Organic Chemistry in Asia (Taiwan), Invited Lecture: The development of chiral proton shuttle catalysts in transition-metal catalysis.

15. 2015/09/06-09, The 6th Japanese-Sino Symposium on Organic Chemistry for Young Scientists (Sendai, Japan), Invited Lecture: Chiral proton shuttle catalysts: applications in carbene insertion reactions and beyond. 

16. 2015/07/11-12, 2nd EOC Symposium (Tianjin), Poster Exhibition: Iron- or copper-catalyzed asymmetric intramolecular cyclopropanation of indoles. (Win Best Poster Award). 

17. 2015/06/28-07/02, The 18th IUPAC Symposium on Organometallic Chemistry Directed toward Organic Synthesis (OMCOS-18) (Sitges, Spain), Poster Exhibition: Highly efficient and practical Fe-catalyzed hydrogenation of olefins.

18. 2014/11/06-09, The 1st EOC Symposium (Kunshan, China), Poster Exhibition: Iron-catalyzed asymmetric transformations of diazo compounds.

19. 2014/08/04-07,中国化学会第29届年会,北京,墙报:钯催化不对称O–H键插入反应。

20. 2014/05/07,华东师范大学,上海,报告题目:手性质子梭催化剂研究进展。 

21. 2014/05/06,复旦大学,上海,报告题目:手性质子梭催化剂研究进展。 

22. 2013/11/08,南京大学“高济宇有机化学前沿讲座”,江苏.南京,报告题目:不对称卡宾插入反应研究进展。

23. 2013/11/07,浙江工业大学“寿恒讲堂”,浙江.杭州,报告题目:不对称卡宾插入反应研究进展。 

24. 2013/10/15-16, Journal of Organic Chemistry & Organic Letters Symposium, (Shanghai, China), Poster Exhibition: Copper-Catalyzed B–H Bond Insertion Reaction.

25. 2013/10/09-12, The Beijing Symposium 2013 on New Frontiers in Organic Chemistry, (Beijing, China), Poster Exhibition: Cooperative Catalysis for Asymmetric Carbene Insertion Reactions.

26. 2013/07/07-10, The 25th International Symposium on Chirality (ISCD-25), (Shanghai, China), Poster Exhibition: Enantioselective Copper-Catalyzed Intramolecular O-H Insertion Reactions. 

27. 2013/03/24, The 3rd CCS-CSJ Young Chemists Forum (Shiga, Japan), Invited Lecture: Iron-catalyzed carbene transfer reactions.

28. 2012/11/09-11, The 12th Tateshina Conference on Organic Chemistry (Nagano, Japan), Poster presentation: Asymmetric carbene insertion reactions cooperatively catalyzed by rhodium and chiral spiro phosphoric acids. 

29. 2011/09/01-05, The 1st Symposium on New Frontiers in Organic Chemistry: Towards Cleaner, Greener Chemical Processes (Beijing), Poster: Transition metal-catalyzed asymmetric heteroatom-hydrogen insertion reactions. (Win Best Poster Award)

30. 2011/07/24-28, The 16th IUPAC Symposium on Organometallic Chemistry Directed toward Organic Synthesis (OMCOS-16) (Shanghai), Oral presentation: Highly enantioselective palladium-catalyzed umpolung allylation reactions.

31. 2010/07/18-23, The 24th International Conference on Organometallic Chemistry (ICOM-24) (Taipei, China), Poster: Highly enantioselective transition metal-catalyzed O–H insertion reactions. (Win Best Poster Award)

32. 2009/10/11-13,第八届全国化学化工学术研讨会,天津,墙报:手性螺环亚磷酸酯配体在钯催化烯丙醇对醛的不对称烯丙基化反应中的应用研究。

33. 2009/08/17-20,中国化学会第6届全国有机化学学术讨论会,陕西.西安,邀请报告:铜催化不对称杂原子-氢键插入反应研究。

34. 2008/07/13-16,中国化学会第26届年会,天津,口头报告:铜催化卡宾对N–H键的不对称插入反应研究。 

35. 2008/06/22-27, The 17th International Conference on Organic Synthesis (ICOS-17) (Daejeon, Korea), Poster: Highly enantioselective insertion of carbenoids into N–H and O–H bonds catalyzed by copper complexes of chiral spiro bisoxazolines. 

36. 2007/04/15-19, The 17th International Conference on Phosphorus Chemistry (ICPC-17) (Xiamen, China), Poster: Synthesis of spirobitetraline phosphoramidite ligand and its application in Rh-catalyzed asymmetric hydrogenation. (Win Best Poster Award)

37. 2004/08/15-19, The 2004 International Symposium on Chiral Synthesis and Drug Design (Tianjin, China), Poster: Electronic effect of chiral spiro monodentate phosphorous ligands in asymmetric hydrogenation.

38. 2004/08/11-14,第三届全国有机化学学术讨论会,甘肃.兰州,墙报:手性螺环单磷配体的电子效应研究。